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There needs to be two women. One who is eeevil, and one who is not. In this case, since you're reversing the idea and having one brainwashed 'good girl', you need one sinister chick who turns out to be on the side of the angels. But remember the usual rule -- the good guy cannot have sex with the bad girl until after his first face-to-face confrontation with the archvillain. Since you're flipping the good and bad girls by this tactic, you have to set it up so that this Jenny chick will be such a 'good girl' that if she falls for a PC, she'll find every excuse NOT to get romantic untl after the PCs have encountered Scorpio.
An interesting notion. I figured that the reason for her mind-control was Scorpio's elixir which made her highly prone to suggestions, Parim then used it to turn her against the PC's. I'd have to create an evil women which the PC's will grasp unto, maybe an Orion or an ex-Romulan spy.